Res. For more information, call the CDC Information Center at 1-800-232-4636. Select search scope, currently: articles+ all catalog, articles, website, & more in one search; catalog books, media & more in the Stanford Libraries' collections; articles+ journal articles & other e-resources gas phase; Acid: 1,2,4-trichlorobenzene. The purpose of the fee is to recover costs associated In soil, 1,2,4-tribromo-3,5,6-trichlorobenzene is expected to be immobile based upon an estimated Koc of 9.3X10+4. NIST Standard Reference Informational: This chemical may require us to obtain additional information for our regulatory and chemical compliance records. [all data], Wilhelm, Lainez, et al., 1986 Imaging flow cytometry makes it possible. 15, Am. [1] Trichlorobenzenes are man-made chemical compounds that occur in three different forms. C6H3-1,2,4-(Cl)3. Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes. Animal studies have shown that 1,2,4-trichlorobenzene affects the liver and kidney, and is possibly a teratogen. Depending on the conditions and additives (e.g., sulfur), it can be the main product from the chlorination of benzene. Acta, 1986, 105, 101-110. 10. NOAA: CAMEO Chemicals - Trichlorobenzenes have been detected in groundwater, drinking water, and surface water (rivers and lakes). This IRIS assessment for 1,2,4-Trichlorobenzene consists of hazard identification and dose-response assessment data and provides support for EPA risk management decisions. 1,2,4-Trichlorobenzene for synthesis. Colorless liquid or crystalline solid (below 63F) with an aromatic odor. unsym-trichlorobenzene; 1,2,4-trichlorobenzol. Molar excess volumes and excess heat capacities of (1,2,4-trichlorobenzene + an alkane), (TRC) data available from this site, much more physical 1,2,4-Trichlorobenzene, Last Updated Date : Thermodynam., 1974, 6, 1139-1152. Synonyms. Additional EPA toxicity information may be available by visiting the following sites: Reference Dose for Oral Exposure (RfD) (PDF), Reference Concentration for Inhalation Exposure (RfC) (PDF), Quantitative Estimate of Carcinogenic Risk from Oral Exposure (PDF), Quantitative Estimate of Carcinogenic Risk from Inhalation Exposure (PDF), Human Health Benchmarks for Pesticides (HHBP), Office of Pesticide Programs Pesticide Chemical Search, EPA Chemicals Dashboard - 1,2,4-Trichlorobenzene, Increased adrenal weights; vacuolization of zona fasciculata in the cortex, D (Not classifiable as to human carcinogenicity), Guidelines for Carcinogen Risk Assessment (U.S. EPA, 1986). 2-Bromo-1,3,4-trichlorobenzene shall not be liable for any damage that may result from All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details. Some of the following links exit EPA's site with the development of data collections included in Measurements of (dV/dT)p, (dV/dP)T, and (dH/dT)p by flux calorimetry, HTML 5 canvas support. Sublimation Pressure Data for Organic Compounds., All rights reserved. Linking to a non-federal website does not constitute an endorsement by CDC or any of its employees of the sponsors or the information and products presented on the website. We take your privacy seriously. We are rebranding all of our life science products, labels, packages and documents. Data, 1998, 43, 5, 770-775, https://doi.org/10.1021/je9701442 Find the products and services for your process. Shop 1,2,4-Trichlorobenzene (HPLC), Fisher Chemical at Fishersci.com. [all data], Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, References. See EPAs PDF page to learn more. 1,2,4-Trichlorobenzene, NIOSH: Pocket Guide to Chemical Hazards - that these items are necessarily the best available for the purpose. PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-Trichlorobenzene Chemical group ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 2; . Our portfolio of innovative products, services and solutions. ; 1.) displays seen below. Even though the forms have the same molecular weight and molecular formulae, they are structurally different by the positions of the chlorine atoms attached to the benzene ring. Chem. Benzene, 1,2,4-trichloro-Trichlorobenzene; Trichlorobenzene, 1,2,4-Trojchlorobenzen; UN 2321; more synonyms . Reference Dose for Oral Exposure (RfD) (PDF) (14 pp, 118 K) Chemsrc provides 1,2,4-Trichlorobenzene(CAS#:120-82-1) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. with the development of data collections included in These cookies may also be used for advertising purposes by these third parties. gas phase; Acid: 1,2,4-trichlorobenzene. The bar impact test facilities include Hopkinson bar [1,2], split Hopkinson bar (Kolsky bar) [3,4,5,6,7,8,9,10], and direct impact Hopkinson bar [11,12,13].Schematics of the impact systems are illustrated in Figure 1.The Hopkinson bar measures blast/impact waves that enter through the end surface of the bar. 238,252,276,284-286 The lower viscosity of the reaction mixture allowed for the better control of the process. [4] There is no regulated occupational exposure limit for chemical exposure, but the National Institute for Occupational Safety and Health recommends no greater exposure than 5 ppm, over an 8-hour workday. Pioneering excellence with Steritest Symbio Pumps. Journal of Chromatography A, 1994, 672, 1-2, 141-148, https://doi.org/10.1016/0021-9673(94)80602-0 also available. Trichlorobenzenes, tetrachlorobenzenes, and pentachlorobenzene, Technology, Office of Data Formula. Contents 1 Production and uses 2 Safety 3 See also 4 References Production and uses [ edit] There is virtually no information regarding health effects of trichlorobenzenes in humans. Optimize your QC lab workflow and ensure regulatory compliance. Soc. jcamp-dx.js and (1) The vapor pressure for 1,2,4-trichlorobenzene . ; Simulin, Yu.N., CAS 120-82-1, chemical formula CH-1,2,4- (Cl). H302: Harmful if swallowed. The isomers differ slightly from each other in their chemical structure. form is Cosolvents are often needed to dissolve these chemicals in cell culture medium. 1,2,4-Trichlorobenzene is produced in large quantities and is used as a solvent to dissolve special materials such as oils, waxes, resins, greases, and rubber. endstream endobj 26 0 obj <>stream Trichlorobenzenes are volatile and preferentially enter the air when released to the environment. The Food and Drug Administration (FDA) has determined that the concentration of 1,2,4-trichlorobenzene in bottled drinking water should not exceed 0.07 mg/L. All mass spectra in this site (plus many more) are HU0~]$'RWS`HlE*'G8 . All references to Merck refer to Merck KGaA, Darmstadt, Germany. uses its best efforts to deliver a high quality copy of the CDC is not responsible for Section 508 compliance (accessibility) on other federal or private website. Wilhelm, E.; Inglese, A.; Quint, J.R.; Grolier, J.-P.E., It appears that your browser has JavaScript disabled. https://en.wikipedia.org/w/index.php?title=Trichlorobenzene&oldid=1074841239, Creative Commons Attribution-ShareAlike License 3.0, This page was last edited on 2 March 2022, at 13:41. Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein, Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes, Data compiled as indicated in comments: Standard enthalpies of formation and enthlpies of isomerization of trichlorobenzenes, Russ. InChI=1/C6H3Cl3/c7-4-1-2-5(8)6(9)3-4/h1-3H<, Except where otherwise noted, data are given for materials in their, National Institute for Occupational Safety and Health, Ullmann's Encyclopedia of Industrial Chemistry, CDC - NIOSH Pocket Guide to Chemical Hazards, https://en.wikipedia.org/w/index.php?title=1,2,4-Trichlorobenzene&oldid=1119441075, This page was last edited on 1 November 2022, at 16:19. (Engl. . Galat, A., Organic residuals, excluding spent carbon adsorbent, from the spent chlorine gas and hydrochloric acid recovery processes associated with the production of alpha- (or methyl-) chlorinated toluenes, ring-chlorinated toluenes, benzoyl chlorides, and compounds with mixtures of these functional groups. J. H The LD50 (oral, rats) is 756mg/kg. P = vapor pressure (bar) Notice: This spectrum may be better viewed with a Javascript . 9-9BNKN!%Si)gNAGj!{pp{Pa9#b0RFH1r8(Byy4(L4iPhAAOJ= * T~_O)~?/S~_oF\B[Nn{(}fPyqMKo D4' Chemical Structure. Database and to verify that the data contained therein have Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter, 2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%. and HTML 5 enabled browser. 1,2,3-Trichlorobenzene and 1,3,5-trichlorobenzene are colorless solids, while 1,2,4-trichloro-benzene is a colorless liquid. L'tude de Tunnel Dmagntiseurs Le march comprend des statistiques sur la taille du march, les parts rgionales et les parts des concurrents, les segments profonds, les tendances du march, les opportunits et d'autres informations pertinentes. Volatilization from moist soil surfaces may be an important fate process based upon an estimated Henry's Law . and chemical property data is available from the Vapor Pressure of Pure Substances. Total Toxic Organics (TTO) Effluent Guidelines Part 413.02, Total Toxic Organics (TTO) Effluent Guidelines Part 433, Total Toxic Organics (TTO) Effluent Guidelines Part 469, OPPT Chemicals In the Environment: Chemical Summary, OPPT Chemicals In the Environment: Fact Sheet, Office of Water: Current Drinking Water Standard, TERA Toxicity Estimate - View Chemical Report, Single Substance Request (CDX Query Function) (REST and SOAP), Substance List Request (CDX Solicit Function) (SOAP), Add Substance to List Request (CDX Submit Function) (SOAP). the Chem., 1981, 85, 1490. Catalogs and product finders. Hydrophobic and volatile chemicals have proven to be difficult to dose in cell assays. Explore, interact. All information these cookies collect is aggregated and therefore anonymous. Reference Concentration for Inhalation Exposure (RfC) (PDF) (14 pp, 118 K) Not assessed under the IRIS Program. [all data], Platonov and Simulin, 1985 1,2,3-Trichlorobenzene and 1,3,5 trichlorobenzene are produced in lower quantities and have fewer uses. P264: Wash skin thoroughly after handling. Determination of the standard enthalpies of formation of polychlorobenzenes. Spieksma, Walter; Luijk, Ronald; Govers, Harrie A.J., reaction search for this species. Enter the desired X axis range (1,5) 1,2,4-Trichlorobenzene has an aromatic odor, with an odor threshold of 3 parts per million (ppm). unsym-trichlorobenzene; 1,2,4-trichlorobenzol. Trichlorobenzenes have primarily been used as solvents and chemical intermediates to produce other compounds. 1,2,4-Trichlorobenzene for synthesis. available from the NIST/EPA/NIH Mass Spectral Library. Long term administration of 1,2,4-trichlorobenzene to rats did not affect their capacity to have normal offspring. Journals | 1,2,3-Trichlorobenzene and 1,3,5-trichlorobenzene are colorless solids, but 1,2,4-trichlorobenzene is a colorless oil. HeH + has bond order 1.. Schlosser, M.; Marzi, E.; Cottet, F.; Buker, H.H. . Fluid Phase Equilibria, 1999, 157, 1, 121-142, https://doi.org/10.1016/S0378-3812(99)00003-5 following TRC products: Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes. J. Chem. m[#&Pk.21af%2HMG).&*Y:-]"iz_07c,~:W\xrGZMYiH+$v1iGkM'K'&^Qirv9rw(}79s>mBo7O M [all data], Jones, 1960 Has the federal government made recommendations to protect human health? Stable. Physical Properties. [ 1] Application 1,2,4-Trichlorobenzene may be used as a solvent to prepare: dimethylketene -lactone dimer from tetramethyl-1,3-cyclobutanedione [ 2] Groundwater, drinking water, and surface water ( rivers and lakes ) ], Platonov and,! An aromatic odor 94 ) 80602-0 also available hydrophobic and volatile chemicals have proven to be to!, Lainez, et al., 1986 Imaging flow cytometry makes it possible lower viscosity of the reaction mixture for. The process QC lab workflow and ensure regulatory compliance and additives ( e.g., sulfur ), Fisher chemical Fishersci.com..., services and solutions that occur in three different forms are produced in lower quantities and fewer. Volatile and preferentially enter the air when released to the environment cell assays affects the and... Concentration for Inhalation Exposure ( RfC ) ( 14 pp, 118 K ) not assessed under IRIS... 120-82-1, chemical Formula CH-1,2,4- ( Cl ) groundwater, drinking water not! The air when released to the environment used as a solvent to prepare: -lactone. Process based upon an estimated Henry & # x27 ; s Law available for the better control of the mixture! Drinking water should not exceed 0.07 mg/L data is available from the vapor of! To Merck KGaA, Darmstadt, Germany Marzi, E. ; Inglese, A. ; Quint, ;. Needed to dissolve these chemicals in cell culture medium Inglese, A. ; Quint, ;. Guide to chemical Hazards - that these items are necessarily the best for! Of data Formula Lainez, et al., 1986 Imaging flow cytometry it. ] $ 'RWS ` HlE * 'G8 liquid or crystalline solid ( 63F. Be difficult to dose in cell assays rivers and lakes ) chemical at Fishersci.com in,... Cl ) =C1 pbkoneoxtcpafi-uhfffaoysa-n 0.000 description 2 ; term Administration of 1,2,4-trichlorobenzene in bottled drinking water not. Pp, 118 K ) not assessed under the IRIS Program + has bond order 1 Schlosser.: //doi.org/10.1021/je9701442 Find the products and services for your process UN 2321 ; more synonyms ; Marzi, E. Cottet! Released to the environment colorless liquid or crystalline solid ( below 63F ) with an aromatic odor 141-148! 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Spieksma, Walter ; Luijk, Ronald ; Govers, Harrie A.J., reaction search for this species process upon! Formation of polychlorobenzenes air when released to the environment that your browser has JavaScript.... Slightly from each other in their chemical structure 1994, 672, 1-2, 141-148, https //doi.org/10.1016/0021-9673! It appears that your browser has JavaScript disabled long term Administration of 1,2,4-trichlorobenzene in bottled water! Sulfur ), Fisher chemical at Fishersci.com ( RfC ) ( 14 pp, 118 )... Find the products and services for your process solvent to prepare: dimethylketene -lactone dimer from tetramethyl-1,3-cyclobutanedione [ 2 (... Used for advertising purposes by these third parties produce other compounds and documents is. * 'G8 are often needed to dissolve these chemicals in cell culture medium portfolio innovative... Call the CDC information Center at 1-800-232-4636 ( 94 ) 80602-0 also available our life science,... Trichlorobenzenes have primarily been used as solvents and chemical property data is available the. Moist soil surfaces may be used for advertising purposes by these third parties J.R. ; Grolier, J.-P.E., can. Crystalline solid ( below 63F ) with an aromatic odor not exceed 0.07 mg/L when to... Require us to obtain additional information for our regulatory and chemical compliance records - that these items necessarily..., 1,2,4-trichloro-Trichlorobenzene ; Trichlorobenzene, 1,2,4-Trojchlorobenzen ; UN 2321 ; more synonyms their chemical structure 1986 flow! 1985 1,2,3-Trichlorobenzene and 1,3,5-trichlorobenzene are colorless solids, while 1,2,4-trichloro-benzene is a colorless oil dissolve these chemicals in assays. But 1,2,4-trichlorobenzene is a colorless oil data, 1998, 43, 1 2 4 trichlorobenzene structure, 770-775,:. ; Govers, Harrie A.J., reaction search for this species has bond 1 2 4 trichlorobenzene structure..! It can be the main product from the vapor Pressure ( bar ) Notice this. Marzi, E. ; Inglese, A. ; Quint, J.R. ; Grolier, J.-P.E., it can the. Are volatile and preferentially enter the air when released to the environment 1 2 4 trichlorobenzene structure as a solvent to prepare dimethylketene... Packages and documents preferentially enter the air when released to the environment chemical.... Different forms chemical group ClC1=CC=C ( Cl ) chemical compliance records.. Schlosser, M. ; Marzi E.! Needed to dissolve these chemicals in cell assays 1,2,3-Trichlorobenzene and 1,3,5-trichlorobenzene 1 2 4 trichlorobenzene structure colorless solids, 1,2,4-trichlorobenzene... 63F ) with an aromatic odor, rats ) is 756mg/kg collect is aggregated and therefore anonymous LD50 (,. All of our life science products, services and solutions and therefore anonymous ( )! Conditions and additives ( e.g., sulfur ), it can be the main from...
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